The van Genuchten PURE LabPollutant Upcycling and Remediation Engineering
Research / Cross-cutting topic

Phosphate recovery from waste streams

Recover useful phosphorus products while understanding and limiting contaminant co-uptake.

Recovery depends on selectivity

Phosphate-rich residuals can also contain arsenic and other contaminants. We investigate the solution chemistry and reaction conditions that allow phosphorus to be recovered while limiting their incorporation into the product.

From extraction solution to calcium phosphate

In sludge research, arsenic extraction and selective reduction can leave a phosphorus-rich solution. We investigate calcium-phosphate precipitation, including the effects of solution composition, calcium-to-phosphorus ratio, and reaction time.

Understanding product structure

Aqueous analyses and synchrotron-based characterization help connect process conditions with the structure and composition of recovered solids.

Groundwater & sludge →   Incinerator ash →
Gloved hand holding a sludge sample mounted for X-ray characterization
Sludge sample prepared for X-ray characterization.

Research in focus

Phosphate recovery characterization figure
Characterization of phosphorus-bearing materials.

Connecting aqueous chemistry and structural characterization

Tinatin Tkesheliadze studies phosphate recovery from waste streams using laboratory experiments and synchrotron techniques.

Meet Tinatin →
From extraction to product structure

Following phosphorus through recovery

The process illustration links arsenic extraction and reduction with calcium-phosphate precipitation. The accompanying data show how recovery experiments and structural characterization can be brought together when assessing the recovered product.

Phosphate recovery process illustration with recovery and structural characterization data
Arsenic separation, calcium-phosphate precipitation, and characterization of the recovered solids. Click to enlarge.
Chemical speciation

Reading the X-ray absorption spectrum

Near-edge spectral features help compare the local chemical environment of phosphorus at different positions in a heterogeneous sludge sample. Interpreting these features requires suitable reference materials and the context provided by the elemental maps.

Phosphorus XANES spectra shown for the pre-extraction sludge example
Phosphorus XANES spectra from the pre-extraction sludge example. Click to enlarge.