The van Genuchten PURE LabPollutant Upcycling and Remediation Engineering
Research / Groundwater & sludge

Groundwater treatment & sludge upcycling

Connect arsenic removal from drinking water with the recovery of arsenic and phosphorus from treatment residuals.

Why treatment residuals matter

Iron-based treatment removes arsenic from groundwater but produces arsenic-bearing sludge. We study the chemistry of these residuals and how they can become sources of recovered arsenic and phosphorus.

Characterize the starting material

Determine arsenic speciation, iron mineral structure, and the associations of phosphorus across sludge sources.

Separate and recover

Investigate chemical extraction and selective transformation of dissolved arsenic into elemental arsenic.

Evaluate the products

Characterize recovered materials and examine phosphate recovery and environmental implications.

Bench-scale electrolysis experiment beside a groundwater treatment sludge suspension
Bench-scale electrolysis and a groundwater treatment sludge suspension.
The scientific approach

Speciation and recovery

Laboratory experiments are combined with synchrotron X-ray characterization to understand the reactions and solids that control recovery.

Explore the methods →
Chemical extraction and separation illustration
Chemical extraction and separation illustration

Related research and news

Selected publications →

Contaminant to Commodity

Learn about the Water4All collaboration and its partners.

Find out more →

Also explore phosphate recovery →

Experimental work

Electrochemical treatment, from bench to tank

Researcher collecting a sample from an electrolysis tank
Sampling during an electrolysis experiment.
Overhead view of an electrode array in an electrolysis tank
Electrode array inside an electrolysis tank.
Molecular-scale evidence

Looking inside treatment residuals

Elemental mapping and spectroscopy help identify associations among iron, calcium, and phosphorus within sludge. These measurements connect the heterogeneous starting material with questions about extraction and recovery.

Phosphorus speciation and elemental mapping overview for groundwater treatment waste
Elemental mapping and phosphorus speciation in groundwater treatment sludge at SSRL. Click to enlarge.
More about the methods →